Product ID:1,2-DINITROGLYCERIN IN ACETONITRILE
MSDS Date:10/24/1996
FSC:6810
NIIN:00N087842
MSDS Number: CHNQL

RADIAN INTERNATIONAL LLC

8501 NORTH MOPAC BLVD
AUSTIN, TX 78720-1088
US

Emergency Phone: 512-454-4797

Info Phone: 512-454-4797

Cage: GO711

RADIAN INTL LLC

201088 AUSTIN, TX 78720-1088 US

Telephone: 512-419-5224

Cage: 29913

1,2-DINITROGLYCERIN

CAS: 621-65-8

RTECS: MA9487000

Fraction By Weight: 0.1%

OSHA PEL N/K

ACGIH TLV: N/K

180F,82C SPEC GRAV

CAS: 75-05-8

RTECS: AL7700000

Fraction By Weight: 99.9%

OSHA PEL 40 PPM

ACGIH TLV: 40 PPM/60 STEL; 9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

5.79 (BUTYL ACETATE = 1)

RTECS: 9999999ZZ

LIQUID, ETHEREAL ODOR.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOS TO ACETONITRILE MAY RESULT IN
CONVUL, COMA, UNCONSCIOUSNESS & DEATH. ACETONITRILE IS A
LACRIMATOR. TOXICOLOGICAL PROPERTIES OF 1,2-DINITROGLYCERIN HAVE
NOT BEEN FULLY INVESTIGATED. IT SHOULD BE ASSUMED TO HAVE TOXIC
EFTS &, THEREFORE, PROCS APPROP FOR SAFE HANDLING OF HAZARDOUS
CHEMICALS SHOULD BE FOLLOWED.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:EXPOS TO ACETONITRILE MAY CAUSE EYE & SKIN
IRRIT, NAUS, VOMIT, CONSTRICTION OF THROAT, CONFUSN, HDCH,
TACHYCARDIA, DYSPNEA, CHEST PAIN, COUGH, BILE-/BLOOD-STAINED
EMESIS, TACHYPNEA, CYANOSIS, LACRIMAT ION, CONVL, COMA, DIARR,
ABDOM PAIN, WEAK, FATIGUE, FLUSHING OF FACE, TIGHTNESS OF CHEST,
DFCLT BRTHG, RESP (SUPDAT)
Medical Cond Aggravated by Exposure:NOT APPLICABLE.

First Aid:INGEST: GIVE VICTIM LARGE QTIES OF LIQUID & TRANSPORT TO MED
FACILITY. IN CASE OF EXTERNAL EXPOS, WASH AFFECTED AREAS W/LARGE
AMTS OF WATER & TRANSPORT TO A MED FACILITY. INHAL: IF BREATHING IS
DISTUR BED, GIVE ARTF RESP WHILE TRANSPORTING TO A MED FACILITY.
EYES: IMMED FLUSH W/POTABLE WATER FOR A MIN OF 15 MIN, SEEK
ASSISTANCE FROM MD . SKIN: FLUSH W/COPIOUS AMTS OF WATER. CALL MD .

Flash Point Method:CC
Flash Point:42.0F,5.6C
Lower Limits:4.4%
Upper Limits:16.0%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE OR HALON EXTINGUISHER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THE VAPOR IS HEAVIER THAN AIR AND MAY
TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. USE ABSORBENT
PAPER TO PICK UP ALL SPILLED MATERIAL. IF NECESSARY, SOAK ABSORBENT
PAPER IN AN APPROPRIATE SOLVENT SUCH AS TOLUENE OR ALCOHOL TO PICK
UP REMAINING TRACES .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:FREEZER. PROTECT FROM LIGHT AND
MOISTURE. DO NOT ALLOW SOLVENT TO EVAPORATE TO DRYNESS.
Other Precautions:ONLY EXPERIENCED PERSONNEL SHOULD BE ALLOWED TO
HANDLE THIS MATERIAL.

Respiratory Protection:AVOID INHALATION OF VAPORS. NIOSH APPROVED
CARTRIDGE TYPE RESPIRATOR WITH NIOSH APPROVED ORGANIC VAPOR
CARTRIDGES RECOMMENDED.
Ventilation:LOCAL EXHAUST: USE WITH FORCED VENTILATION. GENERAL
MECHANICAL: NORMAL LABORATORY AIR EXCHANGE.
Protective Gloves:USE TWO DISSIMILAR TYPES. (SUPDAT)
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . LAB COAT, APRON, OR TYVEK SUIT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID: PERCHLORATES, NITRATING AGENTS, INDIUM, DINITROGEN
TETRAOXIDE. AVOID ALL TYPES OF CONTAMINATION. EFTS OF OVEREXP:
DEPRESSION, SHOCK, DIZZINESS, DROWSINESS, DROP IN BLOOD PRESSURE,
RAPI D PULSE, LASSITUDE, STUPOR, IRRITABILITY, UNCONSCIOUSNESS AND
DEATH. PROT GLOVES: PVC OR NEOPRENE OVER LATEX.

Boiling Pt:B.P. Text:SEE ING 2
Melt/Freeze Pt:M.P/F.P Text:SEE ING 2
Vapor Pres:SEE ING 2
Vapor Density:SEE ING 2
Spec Gravity:SEE ING 2
Evaporation Rate & Reference:SEE INGREDIENT 2
Solubility in Water:SEE INGREDIENT 2
Appearance and Odor:SEE INGREDIENT 2

Stability Indicator/Materials to Avoid:NO
ACIDS, BASES, OXIDIZING AGENTS, REDUCING AGENTS, ALKALI METALS,
NITROGEN-FLUORINE COMPOUNDS, OLEUM, (SUPDAT)
Stability Condition to Avoid:DO NOT ALLOW THE SOLVENT TO EVAPORATE TO
DRYNESS.
Hazardous Decomposition Products:HIGHLY TOXIC FUMES OF CARBON MONOXIDE,
CARBON DIOXIDE, NITROGEN OXIDES AND HYDROGEN CYANIDE.

Waste Disposal Methods:WASTE MATERIALS SHOULD BE DISPOSED OF UNDER
CONDITIONS WHICH MEET FEDERAL, STATE, AND LOCAL ENVIRONMENTAL
CONTROL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.